1.30.2012

Stoichiometry (Quantitative Chemistry)

There is Qualitative Chemistry and Quantitative Chemistry
Under Quantitative Chemistry:
  • Stoichiometry is a branch of chemistry that deals with the quantitative analysis chemical reactions
  • It's a generalization of mole conversions to chemical reactions
  • Understanding the 6 types of Chemical reactions is the foundation of stoichiometry
6 Types of Reactions
  1. synthesis (formation)
  2. Decompostion
  3. Single Replacement (SR)
  4. Double Replacement (DR)
  5. Neutralization
  6. Combustion
Synthesis
A+B>AB
  • usually elements> compounds
  • ex. K + O2 > 2K2O
Decomposition
AB>A+B
  • Reverse of synthesis
    • Always assume the compounds decompose into elements during decomposition
  • Ex. 4H3PO4>6H2+P4 +8O2
Single Replacement (SR)
A+BC>B+AC
  • ex. Ca+2KCL>2K+CaCl2
Double Replacement
AB+CD>AD+BC
  • Ex. MgCl2+K2(SO4)>Mg(SO4)+2KCl
Neutralization (All DR)
Reaction between acid and base
  • Ex. H2SO4+2KOH>2HOH+ K2SO4
Combustion
  • Reaction of something (usually hydrocarbon) with air 
  • Hydro carbon combustion always produces CO2 and H2O
  • Ex. CH4+2O2>CO2+ 2H2O
  • Always balance in the order C, H, then O
http://www.youtube.com/watch?v=XS6JTr-mTWY

1.11.2012

Molecular Formulas

  • If you know an empirical formula to find the molecular formula, you need the molar mass.
ex. The empirical formula for a substance is CH2O and its molar mass is 60.0 g/mol. Determine the molecular formula.

Empirical Formulas

  • Empirical Formulas are the simplest formula of a compound
  • Show only the simplest ratios, not the actual atom
  • Example: the empirical formula for Chlorine gas is Cl
  • Molecular formulas give the actual number of atoms
  • To determine the empirical formula, we need to know the ratio of each atom
  • To determine the ratio, fill in the table below:
ex, A sample of an unknown compound is found to contain 8.4 g of C, 2.1 g of H, and 5.6 g of O. Determine the empirical formula.
  • The simplest ratio may be decimals. For certain decimals, you need to multiply everything by a common number.